Analyses of three-way data from equilibrium and kinetic investigations

Title: Analyses of three-way data from equilibrium and kinetic investigations
Creator: Dyson, Raylene; Maeder, Marcel; Neuhold, Yorck-Michael; Puxty, Graeme
Relation: Analytica Chimica Acta Vol. 490, Issue 1-2, p. 99-108
Publisher Link: http://dx.doi.org/10.1016/S0003-2670(03)00666-4
Publisher: Elsevier BV
Resource Type: journal article
Date: 2003
Description: In kinetic or equilibrium investigations it is common to measure two-way multiwavelength data, e.g. absorption spectra as a function of time or reagent addition. Often it is advantageous to acquire experimental data at various initial conditions or even on different instruments. A collection of these measurements can be arranged in three-dimensional arrays, which can be analysed as a whole under the assumption of a superimposed function, e.g. a kinetic model, and/or common properties of the subsets, such as molar absorptivity. As we show on selected formation equilibria (Zn²⁺/phen) and kinetic studies (Cu²⁺/cyclam) from our own research, an appropriate combination of multivariate data can lead to an improved analysis of the investigated systems.
Subject: metal complexation; three-way data; kinetics; equilibria
Identifier: http://hdl.handle.net/1959.13/33475
Identifier: uon:3225
Identifier: ISSN:0003-2670
Language: eng
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